Spotlighting main group elements in polynuclear complexes
نویسندگان
چکیده
منابع مشابه
Chemical Bonding of Main-Group Elements
Prior to any meaningful discussion of bonding in main-group chemistry, we have to provide a reasonably accurate definition of what a main-group element is. In general, we assume that main-group elements are those that essentially use only their valence sand p-orbitals for chemical bonding. This leads to a number of borderline cases that require closer inspection. Assuming that the outer d-orbit...
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The large number of known stable compounds in which phosphorus has a low coordination number makes it clear that such compounds can no longer be regarded as “exotic” in main group chemistry. While the rich chemistry of P-C multiply bonded systems makes clear their affinity to their organic congeners, iminophosphanes in particular are also of increasing importance. The linkage of a phosphinidine...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2021
ISSN: 2041-6520,2041-6539
DOI: 10.1039/d1sc90011k